The intermediate regime adjacent to the Mott boundary

Whilst superconductivity in the latter seems well described by conventional Bardeen Cooper Schrieffer (BCS) theory, Cs3C60, a Mott Jahn Teller insulator under ambient pressure steroids, exhibits distinctly non BCS type superconductivity upon pressurisation. The intermediate regime adjacent to the Mott boundary, where strong electronic correlations are prominent steroids, was hitherto only studied through physical pressurisation of Cs3C60 to tune the intermolecular spacing. This thesis reports the solid state synthesis of fcc rich RbxCs3xC60 (0.25 x 2) bulk superconducting materials steroids, with excellent stoichiometry control, and the effects on the electronic properties in situ of tuning intermolecular separation by varying temperature steroids, physical and chemical pressurisation via adjusting the cation dopant ratio.

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